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Superstable Pd(0) The carbon-carbon bond-forming reaction using noble metals in Suzuki-Miyaura reaction etc, is one of the reactions essential for the synthesis of pharmaceuticals and functional materials. In particular, the reactions using palladium have widely known though, it has been a problem that the reaction activity became lower depend on catalyst by the oxidization in the air.
Superstable Pd (0) is a zero-valent palladium catalyst with a stability in the air, and shows the good reactivity at a low catalyst amount.


1. Features

  1. Compared to Pd (PPh3)4, a stable zero-valent palladium catalyst
  2. Good reactivity at a low catalyst amount.

features

2. Reaction examples

Reaction example

Reference 1) Daliczek, Z., Soos T., Finta, Z., Timari, G. and Vlad, G. : WO2012/093271.


Product Name Package Size Wako Catalog No. Grade
Tris{tris[3,5-bis(trifluoromethyl)phenyl]phosphine}palladium(0)
【Superstable Pd(0)】
1 g 209-19741 for Organic Synthesis
5 g 205-19743

3. Pd catalyst series

We also provide a large number of the other Pd catalysts.

Palladium(II) Chloride Palladium(II) Acetate Tetrakis(triphenylphosphine) palladium(0) trans-Dichlorobis(triphenylphosphine)
palladium(II)
PdCl2 Pd(OAc)2 Pd(PPh3) 4 Pd(PPh3)2Cl2
[7647-10-1] [3375-31-3] [14221-01-3] [13965-03-2]
162-24711 1 g
168-24713 5 g
160-24712 25 g
165-24701 1 g
161-24703 5 g
163-24702 25 g
206-18391 1 g
202-18393 5 g
204-18392 25 g
042-31471 1 g
048-31473 5 g
040-31472 25 g
Keep at RT. Keep at 2-10°C.

Palladium(II) Nitrate Bis(acetonitrile)dichloropalladium(II) Bis(benzonitrile)dichloropalladium(II) Bis(acetylacetonato)palladium(II)
Pd(NO3)2 Pd(CH3CN)2Cl2 Pd(PhCN)2Cl2 Pd(acac)2
[10102-05-3] [14592-56-4] [14220-64-5] [14024-61-4]
162-24691 1 g
168-24693 5 g
028-17171 1 g
024-17173 5 g
021-17161 1 g
027-17163 5 g
024-17151 1 g
020-17153 5 g
Keep at RT. Keep at 2-10°C.

Bis(dibenzylideneacetone)
palladium(0)
Tris(dibenzylideneacetone)
dipalladium(0)
Tris(dibenzylideneacetone)
dipalladium(0), Chloroform adduct
Bis(tri-o-tolylphosphine)
dibromopalladium(II)
Pd(dba)2 Pd2(dba)3 Pd2(dba)3・CHCl3 C42H42Br2P2Pd 
[32005-36-0] [51364-51-3] [52522-40-4] [24554-43-6]
027-17141 1 g
023-17143 5 g
209-18401 1 g
205-18403 5 g
205-19841 250 mg
201-19843 1 g
209-19844 5 g
022-18551 250 mg
028-18553 1 g
026-18554 5 g
Keep at RT.

[1,4-Bis(diphenylphosphino)butane]
dichloropalladium(II)
[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene]dichloropalladium(II) Dichlorobis[di-t-butyl(p -dimethyl
aminophenyl)phosphino]palladium(II)
Di-μ-chlorobis[(η-allyl)palladium(II)]
Pd(dppb)Cl2 d(Xantphos)Cl2 Pd[P(t-Bu)2(4-(Me2N)
-Ph)]2Cl2
Pd2(η-Allyl)2Cl2
[29964-62-3] [205319-10-4] [887919-35-9] [ - ]
020-18611 1 g
026-18613 5 g
026-18571 1 g
022-18573 5 g
041-31701 250 mg
047-31703 1 g
045-31704 5 g
043-31761 1 g
049-31763 5 g
Keep at RT. Keep at 2-10°C.
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