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Precious Metal Catalysts / Ligands

Precious metal catalysts such as palladium acetate and Tetrakis (triphenylphosphine) palladium for Organic Synthesis have been launched. These are guaranteed for low contents of water and impurity metals that could be interfering factors for the purpose of use as catalysts and can be used safely.



  INDEX
  1. Example of Specifications (palladium (II) Acetate)
  2. Example of Reaction
  3. Product List



1. Example of Specifications (Palladium (II) Acetate)

  • Appearance: Brown powder
  • Solubility in dilute hydrochloric acid: to pass test
  • Loss on drying: max. 2.0%
  • Assay: min. 98.0%
  • Contents of metals: Guaranteed that the contents of Na, Mg, K, Ca, Fe, Cu, Ru, Rh, Pt, etc. are below the specified values.


2. Example of Reaction



3. Product List
3-1. Iridium
The products can be used in boronation of aliphatic compounds and aromatic carbon-hydrogen bond, and carbon-boron bond.

Carbonylhydridotris (triphenylphosphine) iridium (I) Di-μ-chlorobis [(η-cycloocta-1,5-diene) iridium (I) ]
[17250-25-8]
C55H46IrOP3 = 1008.09

250 mg   (Wako Cat. No.039-21811)
        1 g   (Wako Cat. No.035-21813)
[12112-67-3]
C16H24Cl2Ir2 = 671.70

1 g   (Wako Cat. No.041-31441)
5 g   (Wako Cat. No.047-31443)

3-2. Palladium
The products can be used as a catalyst in hydrogenation, oxidation, dehydrogenation, etc. in addition to Suzuki-Miyaura coupling reaction.

Bis(acetylacenato)palladium (II) trans-Dichlorobis
(triphenylphosphine)palladium (II)
Palladium (II) Acetate Palladium (II) Chloride
 
[14024-61-4]
C10H14O4Pd = 304.64

1 g   (Wako Cat. No.024-17151)
5 g   (Wako Cat. No.020-17153)
[13965-03-2]
C36H30Cl2P2Pd = 701.90

  1 g   (Wako Cat. No.042-31471)
  5 g   (Wako Cat. No.048-31473)
25 g   (Wako Cat. No.040-31472)
[3375-31-3]
(CH3COO)2Pd = 224.51

  1 g   (Wako Cat. No.165-24701)
  5 g   (Wako Cat. No.161-24703)
25 g   (Wako Cat. No.163-24702)
[7647-10-1]
PdCl2 = 177.33

  1 g   (Wako Cat. No.162-24711)
  5 g   (Wako Cat. No.168-24713)
25 g   (Wako Cat. No.160-24712)

Palladium (II) Nitrate Tetrakis (triphenylphosphine)
palladium (0)
Tris (dibenzylideneacetone)
dipalladium (0)
 
 
[10102-05-3]
Pd(NO3)2 = 230.43

1 g   (Wako Cat. No.162-24691)
5 g   (Wako Cat. No.168-24693)
[14221-01-3]
C72H60P4Pt = 1155.56

  1 g   (Wako Cat. No.206-18391)
  5 g   (Wako Cat. No.202-18393)
25 g   (Wako Cat. No.204-18392)
[51364-51-3]
C51H42O3Pd2 = 915.72

1 g   (Wako Cat. No.209-18401)
5 g   (Wako Cat. No.205-18403)
 

3-3. Platinum
The product can be used as a catalyst in hydrosilylation of olefins and ketones.

Bis(acetylacetonato)platinum (II) Di-μ-chlorodichlorobis
(ethylene)diplatinum (II)
Hydrogen Hexachloroplatinate
(Ⅳ)Hexahydrate
Platinum (II) Chloride
 
[15170-57-7]
C10H14O4Pt = 393.30

1 g   (Wako Cat. No.022-16851)
5 g   (Wako Cat. No.028-16853)
[12073-36-8]
C4H8Cl4Pt2 = 588.09

250 mg   (Wako Cat. No.042-31591)
    1 g   (Wako Cat. No.048-31593)
[18497-13-7]
H2PtCl6・6H2O = 517.91

  1 g   (Wako Cat. No.080-09241)
  5 g   (Wako Cat. No.086-09243)
25 g   (Wako Cat. No.088-09242)

[10025-65-7]
PtCl2 = 265.99

1 g   (Wako Cat. No.169-24721)
5 g   (Wako Cat. No.165-24723)
Potassium Hexachloroplatinate(Ⅳ) Potassium Tetrachloroplatinate (II)    
   
[16921-30-5]
K2PtCl6 = 486.00

1 g   (Wako Cat. No.163-24741)
5 g   (Wako Cat. No.169-24743)
[10025-99-7]
Cl4K2Pt = 415.09

  1 g   (Wako Cat. No.168-24671)
  5 g   (Wako Cat. No.164-24673)
25 g   (Wako Cat. No.166-24672)
   

3-4. Rhodium
The product can be used in hydrogenation and hydroboration of alkenes, cycloaddition reaction and insertion reaction of carbenes, epoxidization of aldehydes, etc.

Chlorotris(triphenylphosphine)rhodium (I) Hydridotetrakis(triphenylphosphine)rhodium (I) Rhodium (II) Acetate, Dimer
[14694-95-2]
C54H45ClP3Rh = 925.21

1 g   (Wako Cat. No.033-21711)
5 g   (Wako Cat. No.039-21713)
[18284-36-1]
C72H61P4Rh = 1153.06

250 mg   (Wako Cat. No.086-09221)
    1 g   (Wako Cat. No.082-09223)
[15956-28-2]
C8H12O8Rh2 = 441.99

250 mg   (Wako Cat. No.187-02641)
    1 g   (Wako Cat. No.183-02643)

3-5. Ruthenium
The product can be used in hydrogenation reaction, etc.

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium (II) Carbonylchlorohydridotris(triphenylphosphine)ruthenium (II) Tris(2,2'-bipyridyl)ruthenium(II)Dichloride n-Hydrate
[12289-94-0]
C16H26Ru = 319.45

250 mg   (Wako Cat. No.020-16911)
    1 g   (Wako Cat. No. 026-16913)
[16971-33-8]
C55H46ClOP3Ru = 952.40

1 g   (Wako Cat. No.030-21721)
5 g   (Wako Cat. No.036-21723)
[15158-62-0]
C30H24Cl2N6Ru・nH2O

1 g   (Wako Cat. No.207-18441)
5 g   (Wako Cat. No.203-18443)

3-6. Ligands
Ligands for organic synthesis are introduced.
Use them in Suzuki-Miyaura coupling reaction and asymmetric hydrogenation.

1,4-Bis(diphenylphosphino)butane 1,3-Bis(diphenylphosphino)
propane
(S)-(-)-2,2'-Bis[bis
(3,5-di-t-butyl-4-methoxyphenyl)
phosphino]-1,1'-binaphthyl
(S)-(-)-2,2'-Bis
[bis(4-dimethylamino-3,
5-dimethylphenyl)
phosphino]-1,1'-binaphthyl
[7688-25-7]
C28H28P2 = 426.47

  5 g   (Wako Cat. No.020-17011)
25 g   (Wako Cat. No.028-17012)
[6737-42-4]
C27H26P2 = 412.44

  1 g   (Wako Cat. No.027-17021)
  5 g   (Wako Cat. No.023-17023)
25 g   (Wako Cat. No.025-17022)

[541502-07-2]
C80H104O4P2 = 1191.63

250 mg   (Wako Cat. No.028-16951)
    1 g   (Wako Cat. No.024-16953)

[930784-40-0]
C60H68N4P2 = 907.16

250 mg   (Wako Cat. No.025-16961)
    1 g   (Wako Cat. No.021-16963)
5-(Di-t-butylphosphino)-1',3',5'-triphenyl-1,4'-bi-1H-pyrazole Tri-o-tolylphosphine Tri-p-tolylphosphine Tris(4-methoxyphenyl)phosphine
[894086-00-1]
C32H35N4P = 506.62

250 mg   (Wako Cat. No.046-31491)
    1 g   (Wako Cat. No.042-31493)
    5 g   (Wako Cat. No.040-31494)

[6163-58-2]
C21H21P = 304.37

  5 g   (Wako Cat. No.209-18521)
25 g   (Wako Cat. No.207-18522)
[1038-95-5]
C21H21P = 304.37

  5 g   (Wako Cat. No.203-18541)
25 g   (Wako Cat. No.201-18542)
[855-38-9]
C21H21PO3 = 352.36

  5 g (Wako Cat. No.200-18551)
25 g (Wako Cat. No.208-18552)
Tri(2-furyl)phosphine 2-(Di-t-butylphosphino)biphenyl Bis[2-(diphenylphosphino)phenyl]Ether  
 
[5518-52-5]
C12H9O3P = 232.17

1 g   (Wako Cat. No.202-18631)
5 g   (Wako Cat. No.208-18633)

[224311-51-7]
C20H27P = 298.40

1 g (Wako Cat. No.045-31721)
5 g (Wako Cat. No.041-31723)
[166330-10-5]
C36H28OP2 = 538.55

  5 g   (Wako Cat. No.026-17111)
25 g   (Wako Cat. No.024-17112)
 



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