Refer to p.43

Pesticide mixture standard solutions were analyzed in accordance with the simultaneous analysis methods notified by Ministry of Health, Labor and Welfare. The analysis time could be reduced by changing the column size.






ESI, MRM
Ion Spray Voltage : 5500 V (pos), −4500 V (neg)
Temperature : 400℃
Curtein Gas : 20
Collison Gas : 3
Ion Source Gas 1 : 50
Ion Source Gas 2 : 80
System : 3200 Q TRAP (ABI)








Ⅰ-29
sample
(PL-7-2)
Peak No.
Analyte Peak Name Analyte Mass
Ranges
(amu)
Analyte
Retention
Time (min)
Q1 Q3 Mode 2×150
mm
2×100
mm
1 Thiamethoxam 292.0 211.2 5.4 4.0
2 Clothianidin 250.0 132.1 6.4 4.7
3 Chloridazon(PAC) 222.1 77.2 7.4 5.3
4 Thiacloprid 253.0 126.0 8.3 5.9
5 Thiabendazole 202.1 175.1 10.3 7.0
6 Azamethiphos 325.0 183.1 11.0 7.4
7 Dimethirimol 210.2 71.1 13.7 8.8
8 Isoxaflutole 360.1 251.1 14.2 9.0
9 Azinphos-methyl 318.0 132.2 14.9 9.5
10 Pyriftalid 319.1 139.1 15.2 9.6
11 E )-Ferimzone 255.2 91.2 16.0 10.1
12 Z )-Ferimzone 255.2 91.2 16.0 10.1
13 Methoxyphenozide 369.2 149.2 16.3 10.2
14 Iprovalicarb 321.2 119.1 16.8 10.6
15 Chromafenozide 395.2 175.1 16.8 10.5
16 Butafenacil 475.1 331.1 16.8 10.5
17 Simeconazole 294.1 70.1 17.0 10.7
18 Oryzalin 347.1 288.2 17.1 10.7
19 Cyazofamid 325.1 108.2 17.2 10.8
20 Naproanilide 292.1 171.3 17.5 11.0
21 Fenoxycarb 302.2 88.1 17.6 11.0
22 Anilofos 368.1 199.1 18.0 11.3
23 Cyflufenamid 413.0 295.2 18.4 11.6
24 Pyrazolynate
(Pyrazolate)
439.0 91.1 18.7 11.7
25 Indoxacarb
(Indoxacarb-MP)
528.1 203.2 18.8 11.8
26 Benzofenap 431.0 105.2 19.4 12.2
27 Furathiocarb 383.2 195.3 19.6 12.4
28 Cloquintocet-mexyl 336.2 238.2 19.9 12.6
29 Abamectin B1a 890.6 305.3 21.5 13.7


Column : Wakopak® Wakosil-Ⅱ 3C18 HG
Eluent : A)5 mM CH3COONH4 in H2O
B)5 mM CH3COONH4 in CH3OH
Time program :
Column size -
2.0 x 150 mm 2.0 x 100 mm B conc.
0 - 1 min. 0 - 0.6 min. 15 - 40 %
1 - 3.5 min. 0.6 - 2.1 min. 40 %
3.5 - 6 min. 2.1 - 3.6 min. 40 - 50 %
6 - 8 min. 3.6 - 4.2 min. 50 - 55 %
8 - 17.5 min. 4.2 - 10.5 min. 55 - 95 %
17.5 - 30 min. 10.5 - 18 min. 95 %
30 - 40 min. 18 - 28 min. 15 %
Flow Rate : 0.2 mL/min. at 40℃
Injection Vol. : 0.1 ppm、3 μL

Ⅱ-21
sample
(PL-8-1)
Peak No.
Analyte Peak Name Analyte Mass
Ranges
(amu)
Analyte
Retention
Time (min)
Q1 Q3 Mode 2×150
mm
2×100
mm
1 Flumetsulam 326.1 129.1 5.1 3.9
2 Thifensulfuron-
methyl
388.0 167.2 5.8 4.4
3 Florasuram 360.0 129.3 6.5 4.9
4 Cloransulam-
methyl
430.0 398.1 11.1 7.4
5 Diclosulam 406.0 161.1 11.6 7.7
6 Thidiazuron 221.0 102.1 11.6 7.7
7 Forchlorfenuron 248.1 129.2 14.4 9.1
8 Haloxyfop 362.1 316.2 15.6 9.8
1 Gibberellin
(Gibberellin A3)
345.0 142.9 15.6 9.8
2 Fluroxypyr 252.9 194.7 5.8 4.3
3 4-Chlorophenoxyacetic
Acid(4-CPA)
184.9 126.9 7.1 5.1
4 Bromoxynil 275.7 80.8 7.6 5.4
5 1-Naphthaleneacetic
Acid
184.9 141.0 8.5 6.0
6 Cloprop 198.9 126.7 8.7 6.1
7 Ioxynil 369.7 126.8 10.1 6.9
8 Triclopyr 255.8 197.9 11.5 7.6
9 Mecoprop(MCPP) 213.0 140.7 12.2 7.9
10 Dichlorprop 232.9 160.9 12.4 8.0
11 MCPB 227.0 140.9 14.4 9.1
12 Acifluorfen 359.9 316.1 15.0 9.4
13 Fomesafen 437.0 195.0 15.0 9.4




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